许响生

浙江工业大学化学工程学院教授，博导，安全工程学科主任，浙江省应急管理学院副院长。

《化学工艺学》，《药物化学》，《催化作用与催化剂》，《安全工程专业导论》，《应急管理学》，《化工安全与技术》，《化工过程安全》等。

[1] 企事业单位委托科技项目，嘉兴市南湖工业供水有限公司南湖工业水厂一期工程智慧工地试点项目，99.35万元，主持，2023.03-至今；

[2] 企事业单位委托科技项目，南太湖新区第一次自然灾害综合风险（应急管理部分）普查技术服务，163万元，主持，2021.09-至今；

[3] 横向课题，紫外线吸收剂及其中间体的清洁生产工艺研究与开发，280万元，主持，2019.04-至今；

[4] 横向课题，电镀废水重金属回收及资源化利用新工艺开发，325万元，主持，2024.12-至今；

[5] 横向课题，草甘磷复配制剂的研究与开发，12万元，主持，2025.10-至今；

[6] “863”计划，日化和化纤行业细粒子及其前驱物联合控制共性技术与示范应用，41.80万元，主持，2013.01.01-2015.12.31；

[7] 浙江省科技计划项目，年产600吨L-2-氨基丙醇的酸催化加氢还原一步法清洁生产技术，20万元，主持，2009.01.01-2010.12.31.

[8] 国家自然科学基金，原位液相加氢双功能催化剂稳定性研究，35万元，参与，2011.01.01-2012.12.31.

[9] 国家自然科学基金，双环[3.2.0]庚酮类化合物的新反应研究，25万元，参与，2012.01.01-2015.04.27.

[10] 横向课题，激酶类抑制剂关键中间体的技术开发，200万元，参与，2024-09-至今；

[11] 横向课题，马来酸酐接枝聚丙烯的开发，50万元，参与，2022.09.30-至今；

[12] 横向课题，杂环系列药物及其关键中间体的技术开发，105万元，参与，2022.01-至今；

发表文章：

[1] Xiaoqing Li*, Xiaoyu Yan, Zhi Wang, Xiaoxue He, Yuyu Dai, Xinhuan Yan, Deming Zhao, and Xiangsheng Xu*, Complementary Oxidative Generation of Iminyl Radicals from α-Imino-oxy Acids: Silver-Catalyzed C–H Cyanoalkylation of Heterocycles and Quinones, Journal of Organic Chemistry, 2020, 85, 4, 2504–2511.

[2] Kun Zheng, Xiaoyu Yan, Guofu Zhang, Xinhuan Yan, Xiaoqing Li, Xiangsheng Xu*, Photoinduced Carbon Tetrabromide Initiated Aerobic Oxidation of Substituted Toluenes to Carboxylic Acids, Synlett, 2020, 31, 3:272-274.

[3] Jining Quan, Xiaoxue He, Xinhuan Yan, Xiaoqing Li, Xiangsheng Xu*, Synthesis of 5-Iodomethyl Dihydrofurans via t-Butyl Hydroperoxide-Induced Lodocyclization of Olefinic Dicarbonyl Compounds with I₂, Chinses Journal of Organic Chemistry, 2020, 40, 4:1033-1037.

[4] Zhi Wang, Xiaoyu Yan, Xiaoxue He, Xinhuan Yan, Xiaoqing Li, Xiangsheng Xu*, Iminyl-Radical-Mediated Cyanoalkylarylation of Activated Alkenes Enabled by Silver-Catalyzed Decarboxylation of alpha-Imino Oxy Acids, Synlett, 2020, 31, 8:809-812.

[5] Xiaoxue He, Lijie Qian, Yuyu Dai, Xinhuan Yan, Xiaoqing Li, Xiangsheng Xu*, Copper-catalyzed radical oxyallylation of olefins for the construction of alkene-containing isoxazolines, Arkivoc, 2021, 8: 204-216.

[6] Xiaoyu Yan, Xiaoqing Li, Yitu Wang, Yuyu Dai, Xinhuan Yan, Deming Zhao, Xiangsheng Xu*, Iminyl-Radical-Mediated C-C Cleavage/Amination and Alkene Iminoamination Enabled by Visible-Light-Induced Cerium Catalysis, ACS Sustainable Chemistry&Engineering, 2021, 9, 1:101-105.

[7] Zhenming Li∗, Lijie Qian , Huiming Chen , Xiangsheng Xu*, Generation of Iminoxyl Radicals by Photoredox Catalysis Enables Oxidant-Free Hydroxygenation of β,γ-Unsaturated Oximes, Synlett, 2021, 33, 03:293-295.

[8] Yuyu Dai, Xiaoqing Li, Likai Wang, Xiangsheng Xu*, Highly efficient hydrogenation reduction of aromatic nitro compounds using MOF derivative Co–N/C catalyst, New Journal of Chemistry, 2021, 45, 22908.

[9] Yuyu Dai, Yi Wang, Xiaoqing Li, Miao Cui, Yue Gao, Haoran Xu, Xiangsheng Xu*, In situ form core-shell carbon nanotube-imide COF composite for high performance negative electrode of pseudocapacitor, Electrochimica Acta, 2022, 421, 140407.

[10] Hui Yang, Zetian Sun, Huimin Chen, Fenghua Mao, Xiaoqing Li, Xiangsheng Xu*, CuBr₂ catalyzed alkynylation of tertiary methylamine with terminal alkyne using aqueous TBHP under mild conditions, Tetrahedron Letters, 2022, 109, 154136.

[11] Huimin Chen, Zetian Sun, Hui Yang, Fenghua Mao, Xinhuan Yan, Xiaoqing Li, Xiangsheng Xu*, Potassium Persulfate/Tributylamine-Mediated Alkylation/ Annulation of N-Arylacrylamides with Alkyl Iodides, Synlett, 2022, 34, 01:63-66.

[12] Yuyu Dai, Yi Wang, Haoran Xu, Xiaoqing Li, Xinhuan Yan, Xiangsheng Xu*, Structure, morphology and energy storage properties of imide conjugated microporous polymers with different cores and the corresponding composites with CNT, Electrochimica Acta, 2023, 441, 141820.

[13] Xin Wang, Zhelin Mao, Xin Mao, Ximiao Hu, Feiyue Gao, Minrui Gao, Qi-long Wu, Xiao Lyu, Aijun Du, Xiangsheng Xu*, Dual Integrating Oxygen and Sulphur on Surface of CoTe Nanorods Triggers Enhanced Oxygen Evolution Reaction, Advanced Science, 2023, 10.

[14] Zetian Sun, Hui Yang, Huimin Chen, Fenghua Mao, Xiaoqing Li, Xiangsheng Xu*, Photoredox Trifluoromethylation/Cyclization of N-Arylacrylamides with 4-(Difluoroamino)-1-[(trifluoromethyl)sulfonyl]pyridinium Triflate (TFSP), Synlett, 2023, 34, 343-346.

[15] Yuyu Dai, Miao Cui, Xiaoqing Li, Huiming Chen, Xiangsheng Xu*, Polychlorinated Alkylation Annulation of N-arylacrylamide under Electrochemical Conditions, New Journal of Chemistry, 2023, 47, 8355-8362.

[16] Fenghua Mao, Can Jin, Jie Wang, Hui Yang, Xinhuan Yan, Xiaoqing Li, Xiangsheng Xu*, A one-step base-free synthesis of N-arylamides via modified pivaloyl mixed anhydride mediated amide coupling, Organic & Biomolecular Chemistry, 2023, 21, 3825-3828.

[17] Hui Yang, Shaowen Wang, Jie Wang, Xiangsheng Xu*, Xiaoqing Li, Gold catalyzed hydrofluorination of propargyl alcohols promoted by fluorine-hydrogen bonding, Chemical Communications, 2023, 59, 9078-9081.

[18] Hui Yang, Jie Wang, Can Jin, Xiaoqing Li, Xiangsheng Xu*, Au(I)-Catalyzed Regioselective Hydrofluorination of Propargylamines Using Aqueous HF, Journal of Organic Chemistry, 2023, 88, 12074-12078.

[19] Yuyu Dai, Haoran Xu, Jiapeng Huang, Erling Dai, Xiangsheng Xu*, A Co/Cu-based bimetallic metal organic framework for high performance hybrid supercapacitors, Journal of Energy Storage, 2024, 88, 111623.

[20] Zetian Sun, Jianting Zhang, Xiaohua Du, Lulu Liu, Shuo Gao, Chenchen Qi, Xiaoqing Li, Xiangsheng Xu^*, Photoinduced EnT-mediated sulfonamidylimination of alkenes and (hetero)arenes with iminophenylacetic acid oxime esters, Chemical Communications, 2024, 60, 7934-7937.

授权专利：

[1] 许响生，俞雪萍，王志，李小青，一种5-取代四氮唑类化合物的合成方法，CN201910019599.6，2020-07-21.

[2] 李小青，陈昆，许响生，一种β-碘代-N-烷氧基苯并三氮唑类化合物的合成方法，CN201710545949.3，2020-10-09.

[3] 李小青，钱黎杰，丁宇，许响生，一种卤代异噁唑啉类化合物的合成方法，CN201910682475.6，2021-01-26.

[4] 李小青，闫晓雨，许响生，一种氰烷基取代的氮杂环化合物及其合成方法，CN 201911283722.1，2021-05-25.

[5] 许响生，王志，李小青，一种傅-克反应微通道法合成三嗪类化合物的方法，CN 202010070615.7，2021-06-29.

[6] 李小青，闫晓雨，许响生，一种氰烷基取代的醌类化合物及其合成方法，CN 201911282454.1，2022-03-25.

[7] 李小青，郑昆，许响生，一种苯甲酸类化合物的合成方法，CN 201910859249.0，2022-04-29.

[8] 李小青，闫晓雨，许响生，一种γ-肼基氰化合物及其合成方法，CN 202011239585.4，2022-07-01.

[9] 李小青，何小雪，许响生，一种带烯烃侧链的异噁唑啉衍生物及其合成方法，CN 202011487288.1，2022-07-26.

[10] 许响生，王力凯，李小青，一种芳香族硝基化合物催化加氢还原的方法，CN 202010070621.2，2023-05-16.

[11] 李小青，毛凤华，杨惠，许响生，一种合成酰胺类化合物的方法CN202211057635.6，2023-12-05.

[12] 任杰，许响生，李小青，戴玉玉，金辉，一种重整芳烃精制方法，CN202210619157.7，2024-01-12.

[13] 任杰，许响生，李小青，戴玉玉，金辉，具有介孔结构的三氧化钨/二氧化锆复合氧化物固体酸催化剂及其制备与应用，CN202210618572.0，2024-07-19.

[14] 任杰，许响生，李小青，戴玉玉，金辉，一种合成直链烷基芳烃的方法，CN202210619152.4，2024-07-19.